Reaktion #499688

ord-8b11187b3ec94ad888c5af91e5d386aa

Reaktionsgleichung

[Cl-].[Cl-].[Cl-].[Cl-].[Zr+4]
zirconium tetrachloride
[Al+3].[Cl-].[Cl-].[Cl-]
aluminum trichloride
ClCCl
methylene chloride
→
[Al+3].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Zr+4]
AlCl3 ZrCl4

Edukte

[Cl-].[Cl-].[Cl-].[Cl-].[Zr+4]
zirconium tetrachloride
[Al+3].[Cl-].[Cl-].[Cl-]
aluminum trichloride
—
Zr nitro
ClCCl
methylene chloride

Reagenzien

Keine

Lösungsmittel

C[N+](=O)[O-]
nitromethane

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

1.2 g (5.1 mmol) of zirconium tetrachloride and 6.2 g (46.5 mmol) of aluminum trichloride were placed in a two-necked round-bottomed flask under an argon atmosphere. 410 ml of methylene chloride and 23 ml (25.9 g) of nitromethane were added (ratio Zr/nitro compound 1:82.5).

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US06562916B2uspto-grants-2003_05