Reaktion #487527

ord-63837604956d4726a6cfde2531fe8fe5

Reaktionsgleichung

$CCCCCCCC/C=C\CCCCCCCC(=O)Cl$

Oleoyl chloride

$CCCCCCCC/C=C\CCCCCCCCCCCC(=O)O$

Erucic acid

→

CCCCCCCCC=CCCCCCCCCCCCCOC(=O)CCCCCCCC=CCCCCCCCC

Compound D

Ausbeute 94.5%

Octadec-9-enoic acid docos-13-enyl ester

Ausbeute 94.5%

Edukte

—

compounds D2

—

$CCCCCCCC/C=C\CCCCCCCC(=O)Cl$

Oleoyl chloride

$CCCCCCCC/C=C\CCCCCCCCCCCC(=O)O$

Erucic acid

—

compound D

Reagenzien

Keine

Lösungsmittel

Ethyl acetate Hexane

Reaktionsbedingungen

Detaillierte Bedingungen

See reaction.notes.procedure_details.

Vorschrift

Compound D was prepared from Oleoyl chloride and Erucic acid following the general procedure discussed before and as shown in FIG. 9. Pure compound D was a colorless oil obtained by column chromatography with Ethyl acetate/Hexane=1:40. Reaction conditions for branched derivative compounds D2, D3, and D4 are also shown below.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US08741822B2uspto-grants-2014_06