Reaktion #486477

Reaktionsgleichung

(Tetramethylcyclopentadienyl)(diphenylmethyl)dimethylsilane dipotassium salt

zirconium tetrachloride

→

desired product

(tetramethylcyclopentadienyl)(diphenylmethyl)dimethylsilane zirconium dichloride

Lösungsmittel

toluene

Reaktionsbedingungen

Aufarbeitung

1. 1
   Filtrationfiltered
2. 2
   SonstigeThe solvent was removed under vacuum
3. 3
   WaschenThe residue was washed with hexane
4. 4
   Filtrationfiltered
5. 5
   Waschenwashed again with hexane
6. 6
   Sonstigedried

Vorschrift

(Tetramethylcyclopentadienyl)(diphenylmethyl)dimethylsilane dipotassium salt (3.00 g, 7.10 mmol) was combined with 1.654 grams of zirconium tetrachloride in 150 mL of toluene at about 25° C. The reaction mixture was stirred overnight at about 25° C., and then filtered. The solvent was removed under vacuum. The residue was washed with hexane and filtered, washed again with hexane and dried to give the desired product as a red-orange solid.

Quelle