Reaktion #485439

ord-306acd8ff5604fdfa490f0516c6cc019

Reaktionsgleichung

[CH3][Zr]([CH3])([CH3])([CH3])([CH3])[CH]1C=CC=C1.[Cl-].[Cl-].[Cl-]
pentamethylcyclopentadienylzirconium trichloride
CN(C)CCCC1C=Cc2ccccc21
1(N,N-dimethylaminopropyl)indene
CN(C)CCC1=CC=CC1
(N,N-dimethylaminoethyl)cyclopentadiene
[Cl-].[Cl-].[Cl-].[Zr+3][CH]1C=CC=C1
cyclopentadienylzirconium trichloride
→
CN(C)CCCC1[C]([Zr+2][CH]2C=CC=C2)=Cc2ccccc21.[Cl-].[Cl-]
[1-(N,N-Dimethylaminopropyl)indenyl](cyclopentadienyl)zirconium Dichloride
Ausbeute 40.0%

Edukte

[CH3][Zr]([CH3])([CH3])([CH3])([CH3])[CH]1C=CC=C1.[Cl-].[Cl-].[Cl-]
pentamethylcyclopentadienylzirconium trichloride
CN(C)CCCC1C=Cc2ccccc21
1(N,N-dimethylaminopropyl)indene
CN(C)CCC1=CC=CC1
(N,N-dimethylaminoethyl)cyclopentadiene
[Cl-].[Cl-].[Cl-].[Zr+3][CH]1C=CC=C1
cyclopentadienylzirconium trichloride

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

Example 1 was repeated in the same manner as described except that 1(N,N-dimethylaminopropyl)indene was substituted for (N,N-dimethylaminoethyl)cyclopentadiene and that cyclopentadienylzirconium trichloride was substituted for pentamethylcyclopentadienylzirconium trichloride. The yield was 40.0%. The physical properties of the product are as follows:

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US06610872B1uspto-grants-2003_08