Reaktion #483530

ord-a7c8de74fa7b4a0d849fbb2e816c55a4

Reaktionsgleichung

COc1ccc2c(C(=O)Cl)c(C)c(-c3ccccc3)nc2c1
3-methyl-7-methoxy-2-phenylquinoline-4-carbonylchloride
CC[C@H](N)c1ccccc1
(S)-(−)-a-ethylbenzylamine
CC[C@H](NC(=O)c1c(C)c(-c2ccccc2)nc2cc(OC)ccc12)c1ccccc1
(S)-N-(α-Ethylbenzyl)-3-methyl-7-methoxy-2-phenylquinoline-4-carboxamide

Lösungsmittel

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    SonstigePrepared

Vorschrift

Prepared as described in Ex. 1, starting from 1.27 g ( 4.09 mmol) of crude 3-methyl-7-methoxy-2-phenylquinoline-4-carbonylchloride, 0.55 g (4.09 mmol) of (S)-(−)-a-ethylbenzylamine and 1.71 ml (12.27 mmol) of TEA in 24 ml of dry CH2Cl2 and 1 ml of DMF to help solubility. The reaction mixture was stirred 12 hours at room temperture.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US06608083B1uspto-grants-2003_08