Reaktion #48147

ord-2e61059cfd6d4154b127a196e0f3dd59

Reaktionsgleichung

CC(C)N1CCC(Oc2ccc3[nH]c(C(=O)N4CCOCC4)cc3c2)CC1
[5-(1-isopropyl-piperidin-4-yloxy)-1H-indol-2-yl]-morpholin-4-yl-methanone
CC(C)N1CCC(Oc2ccc3[nH]c(C(=O)N4CCOCC4)cc3c2)CC1
intermediate 2
CC(C)N1CCC(Oc2ccc3[nH]c(C(=O)N4CCOCC4)cc3c2)CC1
[5-(1-isopropyl-piperidin-4-yloxy)-1H-indol-2-yl]-morpholin-4-yl-methanone
Cc1ccc(B(O)O)cc1
4-methylbenzeneboronic acid
Cc1ccc(-n2c(C(=O)N3CCOCC3)cc3cc(OC4CCN(C(C)C)CC4)ccc32)cc1
title compound
Cc1ccc(-n2c(C(=O)N3CCOCC3)cc3cc(OC4CCN(C(C)C)CC4)ccc32)cc1
[5-(1-Isopropyl-piperidin-4-yloxy)-1-p-tolyl-1H-indol-2-yl]-morpholin-4-yl-methanone

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    SonstigeIn analogy to the procedure described for the synthesis of example 6

Vorschrift

In analogy to the procedure described for the synthesis of example 6, the title compound was synthesized from [5-(1-isopropyl-piperidin-4-yloxy)-1H-indol-2-yl]-morpholin-4-yl-methanone (intermediate 2) and 4-methylbenzeneboronic acid. The title compound was obtained in 57% yield as a yellow foam. MS (m/e): 462.2 (MH+, 100%).

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US07745479B2uspto-grants-2010_06