Reaktion #468612

ord-37064c34cb934269aea83faa0fc4223b

Reaktionsgleichung

CCOC(=O)/C=C/C=C/c1ccc(C(F)(F)F)cc1
Ethyl (2E,4E)-5-[4-(trifluoromethyl)phenyl]-2,4-pentadienoate
CC(C)[CH2][Al][CH2]C(C)C
diisobutyl aluminum
→
OC/C=C/C=C/c1ccc(C(F)(F)F)cc1
title compound
OC/C=C/C=C/c1ccc(C(F)(F)F)cc1
(2E,4E)-5-[4-(Trifluoromethyl)phenyl]-2,4-pentadien-1-ol

Edukte

CCOC(=O)/C=C/C=C/c1ccc(C(F)(F)F)cc1
Ethyl (2E,4E)-5-[4-(trifluoromethyl)phenyl]-2,4-pentadienoate
CC(C)[CH2][Al][CH2]C(C)C
diisobutyl aluminum

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

Ethyl (2E,4E)-5-[4-(trifluoromethyl)phenyl]-2,4-pentadienoate was treated with diisobutyl aluminum hybride in the same manner as in Reference example 21 to obtain the title compound in quantitative yield.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US06306880B1uspto-grants-2001_10