Reaktion #46062

Reaktionsgleichung

4-bromo-2,6-dimethylaniline

sodium hydroxide

sodium formate

→

Compound 1a

3,3′,5,5′-tetramethylbiphenyl-4,4′-diamine

Lösungsmittel

water

Reaktionsbedingungen

Vorschrift

Compound 1a was prepared using the procedure described in P. Bamfield and P. M. Quan, Synthesis, 1978, 537 using 4-bromo-2,6-dimethylaniline (10.00 g, 50 mmol), CTAB (2.00 g, 5.5 mmol, 0.11 eq.), 5% palladium on charcoal (0.80 g, 50% paste), sodium hydroxide (21.1 ml, 8.0M, 0.169 mol) and sodium formate (2×3.40 g, 100 mmol, 2 eq.) in water (30 ml).

Quelle