Reaktion #45986

ord-27ff517a489648c99cf4d73f62a9a386

Lösungsmittel

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    FiltrationThe reaction mixture was then filtered
  2. 2
    Sonstigeto remove the catalyst
  3. 3
    SonstigeThe solvent was removed in vacuuo

Vorschrift

The nitro intermediate (10 mmol) obtained above was dissolved in EtOAc (50 mL) and hydrogenated in the presence of 10% Pd/C (360 mg) until completion according to General Procedure H, as indicated by TLC or HPLC. The reaction mixture was then filtered to remove the catalyst. The solvent was removed in vacuuo to afford the desired 4-(6-methoxy-naphthalen-2-yloxy)aniline, which was used directly for further transformation without further purification.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US07737285B2uspto-grants-2010_06