Reaktion #4595

Reaktionsgleichung

magnesium chloride ethanol

magnesium chloride

2-ethyl-1-hexanol

→

magnesium chloride 2-ethylhexanol

Lösungsmittel

ethanol

Reaktionsbedingungen

Aufarbeitung

1. 1
   workup.DISTILLATIONThe solution was then distilled at 120° C.
2. 2
   Sonstigeto remove ethanol and heptane
3. 3
   workup.ADDITIONDecane (97.7 g) was added to the resulting viscous solution

Vorschrift

To a sample (50 g, 0.134 mole) of magnesium chloride ethanol adduct prepared as in Example 2 and having an ethanol:magnesium chloride ratio of 6 was added 60 ml of 2-ethyl-1-hexanol. The solution was then distilled at 120° C. to remove ethanol and heptane. Decane (97.7 g) was added to the resulting viscous solution to obtain the magnesium chloride-2-ethylhexanol adduct as a clear, colorless solution. It had a molar ratio of 2-ethylhexanol:magnesium chloride of 2.9 and still contained approximately 1% ethanol.

Quelle