Reaktion #457700

ord-87e7e1d3f09947258c8930b5f8efa942

Reaktionsgleichung

CC1(C)CC(N)CC(C)(C)N1
4-amino-2,2,6,6-tetramethylpiperidine
OCCCCCCO
1,6-hexanediol
[H][H]
hydrogen
→
CC1(C)CC(NCCCCCCNC2CC(C)(C)NC(C)(C)C2)CC(C)(C)N1
N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine

Edukte

CC1(C)CC(N)CC(C)(C)N1
4-amino-2,2,6,6-tetramethylpiperidine
OCCCCCCO
1,6-hexanediol
[H][H]
hydrogen

Reagenzien

—
reduced copper chromite

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    Sonstigeis reacted in a 1-liter shaft oven which

Vorschrift

A mixture of 4-amino-2,2,6,6-tetramethylpiperidine and 1,6-hexanediol in a molar ratio of 4:1 is reacted in a 1-liter shaft oven which is filled with 500 ml of reduced copper chromite catalyst (Harshaw Cu 1107 of Harshaw Chemical Co, DE-5632 Wermelskirchen) at 180° C. and 30 bars of hydrogen hourly.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04526971uspto-grants-1985_07