Reaktion #451333

Reaktionsgleichung

allylmethylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride

allylamine

→

Allylmethylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid N-allylimide

Reaktionsbedingungen

Aufarbeitung

1. 1
   Temperaturis heated
2. 2
   Temperaturat reflux temperature for 2 hours
3. 3
   Sonstigewater is removed by distillation
4. 4
   Sonstigeis rectified at 119°-127° C.

Vorschrift

A mixture of 30 g of allylmethylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride and 9.41 g of allylamine is heated at reflux temperature for 2 hours, water is removed by distillation, and the product is rectified at 119°-127° C. and 2.66 Pa. This gives 30.24 g (85.5% of theory) of a pale yellow oil having the following characteristic data: nD20 =1.5202, η25 =0.135 Pa.s.

Quelle