Reaktion #44403

ord-1de1c76028714783b37af19742ced946

Reaktionsgleichung

CCN(CC)c1ccc(N)cc1
N,N-diethyl-1,4-diamino-benzene
O=S([O-])([O-])=S
thiosulfate
→
CCN(CC)c1ccc(N)c(SS(=O)(=O)O)c1
thiosulfuric acid S-(2-amino-5-diethylamino-phenyl)ester

Edukte

CCN(CC)c1ccc(N)cc1
N,N-diethyl-1,4-diamino-benzene
O=S([O-])([O-])=S
thiosulfate

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

In this step, an N,N-diethyl-1,4-diamino-benzene, 15, is oxidized in the presence of a thiosulfate to give a thiosulfuric acid S-(2-amino-5-diethylamino-phenyl)ester, 16, as illustrated in the following scheme:

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US07737138B2uspto-grants-2010_06