Reaktion #441799

ord-d524baec9fd0403192822ba1bbb041a5

Reaktionsgleichung

Cc1ccccc1[N+](=O)[O-]
o-nitrotoluene
→
Cc1ccccc1NNc1ccccc1C
o-hydrazotoluene
Ausbeute 93.0%

Edukte

Cc1ccccc1[N+](=O)[O-]
o-nitrotoluene

Reagenzien

Keine

Lösungsmittel

CS(C)=O
dimethyl sulfoxide

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    workup.ADDITIONwas added to the reaction mixture

Vorschrift

An identical reduction of o-nitrotoluene as described in example 7 was carried out, except 1.8 g of dimethyl sulfoxide was added to the reaction mixture. This reduction resulted in a 93% yield of o-hydrazotoluene.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04375559uspto-grants-1983_03