Reaktion #441798

ord-ea501985d45b4412a6cbb5a2c923ba57

Reaktionsgleichung

Cc1ccccc1[N+](=O)[O-]
o-nitrotoluene
→
Cc1ccccc1NNc1ccccc1C
o-hydrazotoluene
Ausbeute 54.0%

Edukte

Cc1ccccc1[N+](=O)[O-]
o-nitrotoluene

Reagenzien

Keine

Lösungsmittel

CO
methanol

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    SonstigeThe reduction products were isolated

Vorschrift

The identical reduction of o-nitrotoluene as described in example 5 was carried out except 68 g of absolute methanol was used in place of the 95% ethanol. The reduction products were isolated using the same procedures and a 54% yield of o-hydrazotoluene was recovered.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04375559uspto-grants-1983_03