Reaktion #43566

ord-3c57686b1d0049178aa5b0b71d067ff8

Reaktionsgleichung

C=C1CCC(C(=O)OCC)CC1
4-methylene-cyclohexanecarboxylic acid ethyl ester
[Al+3].[H-].[H-].[H-].[H-].[Li+]
LAH
→
C=C1CCC(CO)CC1
(4-methylene-cyclohexyl)-methanol

Edukte

C=C1CCC(C(=O)OCC)CC1
4-methylene-cyclohexanecarboxylic acid ethyl ester
[Al+3].[H-].[H-].[H-].[H-].[Li+]
LAH

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    workup.DISTILLATIONThe product was purified by distillation

Vorschrift

The reduction reaction of 4-methylene-cyclohexanecarboxylic acid ethyl ester with LAH is as described in the above reference. The product was purified by distillation to provide (4-methylene-cyclohexyl)-methanol as clear oil (3.67 g, 29.09 mmol, 50% over Step A and B).

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US07732449B2uspto-grants-2010_06