Reaktion #433166

Reaktionsgleichung

2,4-dichloro-6-(2,2,6,6-tetramethylpiperidin-1-yl)-1,3,5-triazine

isopropylamine

→

2,4-bis-isopropylamino-6-(2,2,6,6-tetramethylpiperidin-1-yl)-1,3,5-triazine

Lösungsmittel

xylene

Reaktionsbedingungen

Aufarbeitung

1. 1
   Waschenthe autoclave contents are washed three times
2. 2
   Trockneneach with 100 ml of water, and the yellowish xylene solution is dried over sodium sulfate
3. 3
   Filtrationfiltered
4. 4
   Sonstigeevaporated

Vorschrift

43.4 g of 2,4-dichloro-6-(2,2,6,6-tetramethylpiperidin-1-yl)-1,3,5-triazine are heated in an autoclave to 160° for 8 hours with 39.0 g of isopropylamine in 200 ml of xylene. After cooling to room temperature, the autoclave contents are washed three times, each with 100 ml of water, and the yellowish xylene solution is dried over sodium sulfate, stirred for 10 minutes with 5 g of Tonsil Optimum (bleaching earth), filtered and evaporated. The 2,4-bis-isopropylamino-6-(2,2,6,6-tetramethylpiperidin-1-yl)-1,3,5-triazine obtained is a slightly yellowish resin which could not be crystallized.

Quelle