Reaktion #429531

Reaktionsgleichung

1,1-ethylenedioxy-4-hydroxy-4-(4-n-propylphenyl)cyclohexane

→

1,1-ethylenedioxy-4-(4-n-propylphenyl)-4-cyclohexene

Ausbeute 98.2%

Lösungsmittel

toluene

Reaktionsbedingungen

Aufarbeitung

1. 1
   workup.ADDITIONwas added as catalyst
2. 2
   Temperatura reflux for 2 hours
3. 3
   TemperaturAfter the reaction solution was cooled
4. 4
   Filtrationthe catalyst was filtered off
5. 5
   WaschenOrganic layer was washed with water
6. 6
   Trocknendried over anhydrous magnesium sulfate
7. 7
   workup.DISTILLATIONthe solvent was distilled off under a reduced pressure

Vorschrift

To 500 ml of toluene was dissolved 98 g of the 1,1-ethylenedioxy-4-hydroxy-4-(4-n-propylphenyl)cyclohexane mentioned above, 5 g of Amberlist 15E was added as catalyst thereto, and stirred under a reflux for 2 hours. After the reaction solution was cooled, the catalyst was filtered off. Organic layer was washed with water and dried over anhydrous magnesium sulfate, and the solvent was distilled off under a reduced pressure to obtain 90 g of 1,1-ethylenedioxy-4-(4-n-propylphenyl)-4-cyclohexene.

Quelle