Reaktion #4219

ord-95fce6ee0fd6497e86db89788ce9af11

Reaktionsgleichung

N#Cc1cccc(C=O)c1
Meta-cyanobenzaldehyde
CCC(O)CNc1ccc(Cl)c(C(F)(F)F)c1
1-(3-trifluoromethyl-4-chlorophenylamino)-2-butanol
O
water
CCC1CN(c2ccc(Cl)c(C(F)(F)F)c2)C(c2cccc(C#N)c2)O1
2-m-Cyanophenyl-3-(3-trifluoromethyl-4-chlorophenyl)-5-ethyl oxazolidine

Lösungsmittel

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    workup.ADDITIONwas added
  2. 2
    Sonstigethe mixture was stripped on a rotary evaporator

Vorschrift

Meta-cyanobenzaldehyde (2.1 g, 0.016 mole) was added to 4.3 g of 1-(3-trifluoromethyl-4-chlorophenylamino)-2-butanol in 50 ml of toluene and 2-3 drops of methane sulfonic acid was added. The mixture was refluxed under a modified Dean-Stark apparatus until no more water came off and the mixture was stripped on a rotary evaporator. Yield was 6 g of product, nD30 1.5774. It was characterized by IR and NMR.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04723986uspto-grants-1988_02