Reaktion #419897

Reaktionsgleichung

rongalit

tertiary butyl hydroperoxide

styrene

tertiary butyl hydroperoxide

disodium ethylenediaminetetraacetate

styrene

acrylonitrile

acrylonitrile

rongalit

→

acrylonitrile-styrene copolymer

Lösungsmittel

water

water

Reaktionsbedingungen

Aufarbeitung

1. 1
   Sonstigedecreased to 60° C.
2. 2
   workup.ADDITIONwas added
3. 3
   workup.ADDITIONwas added dropwise over about 1 hour
4. 4
   Sonstigepolymerization
5. 5
   workup.ADDITIONAfter the dropwise addition
6. 6
   workup.ADDITIONwas added with an aqueous solution
7. 7
   workup.ADDITIONwas added dropwise over about 40 minutes
8. 8
   Sonstigepolymerization
9. 9
   workup.ADDITIONAfter the dropwise addition
10. 10
    workup.WAITto stand for 1 hour
11. 11
    Temperaturwas cooled down

Vorschrift

After the solution temperature inside the reactor vessel decreased to 60° C., an aqueous solution having 0.4 parts of rongalit dissolved in 10 parts of distilled water was added. Next, a mixed solution including 11.1 parts of acrylonitrile, 33.2 parts of styrene, and 0.2 parts of tertiary butyl hydroperoxide was added dropwise over about 1 hour to effect polymerization. After the dropwise addition, the solution was allowed to stand for 1 hour, and then was added with an aqueous solution having 0.0002 parts of ferrous sulfate, 0.0006 parts of disodium ethylenediaminetetraacetate, and 0.25 parts of rongalit dissolved in 10 parts of distilled water. Next, a mixed solution including 7.4 parts of acrylonitrile, 22.2 parts of styrene, and 0.1 part of tertiary butyl hydroperoxide was added dropwise over about 40 minutes to effect polymerization. After the dropwise addition, the solution was allowed to stand for 1 hour, and then was cooled down, thereby yielding a graft copolymer latex in which an acrylonitrile-styrene copolymer was grafted to the composite rubber consisting of polyorganosiloxane and the butyl acrylate rubber.

Quelle