Reaktion #419609

ord-545e0b0acb5140a78d71ff0acb464d41

Reaktionsgleichung

Cc1onc(-c2ccccc2)c1COc1ccc(C(=O)O)cn1
6-(5-methyl-3-phenyl-isoxazol-4-ylmethoxy)-nicotinic acid
CC(C)[C@H](N)CO
L-valinol
Cc1onc(-c2ccccc2)c1COc1ccc(C(=O)N[C@H](CO)C(C)C)cn1
title compound
Ausbeute 86.0%
Cc1onc(-c2ccccc2)c1COc1ccc(C(=O)N[C@H](CO)C(C)C)cn1
N—((S)-1-Hydroxymethyl-2-methyl-propyl)-6-(5-methyl-3-phenyl-isoxazol-4-ylmethoxy)-nicotinamide
Ausbeute 86.0%

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

As described for example 191, 6-(5-methyl-3-phenyl-isoxazol-4-ylmethoxy)-nicotinic acid (200 mg, 0.65 mmol) was converted, using L-valinol instead of 2-aminoethyl isopropylether, to the title compound (220 mg, 86%) which was obtained as a white solid. MS: m/e=394.2 [M−H]−.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US08877783B2uspto-grants-2014_11