Reaktion #417750

Reaktionsgleichung

2-Bromo-3,4,5-trimethoxybenzaldehyde dimethyl-acetal

3-ethoxy-4-methoxybenzaldehyde

dimethyl acetylenedicarboxylate

→

1-(3-ethoxy-4-methoxyphenyl)-2,3-bis(methoxycarbonyl)-4-hydroxy-6,7,8-trimethoxynaphthalene

Ausbeute 65.0%

Reaktionsbedingungen

Vorschrift

2-Bromo-3,4,5-trimethoxybenzaldehyde dimethyl-acetal, 3-ethoxy-4-methoxybenzaldehyde and dimethyl acetylenedicarboxylate are treated in the same manner as described in Example 1, whereby 1-(3-ethoxy-4-methoxyphenyl)-2,3-bis(methoxycarbonyl)-4-hydroxy-6,7,8-trimethoxynaphthalene is obtained as colorless needles.

Quelle