Reaktion #415743

ord-c6d8b3a5792f42c789ae2ac50ddf562d

Reaktionsgleichung

NS(=O)(=O)[O-].NS(=O)(=O)[O-].NS(=O)(=O)[O-].[Al+3]
aluminum sulfamate
NCCC(=O)O
β-alanine
O=C([O-])[O-].[Mg+2]
magnesium carbonate
OBr
hydroxybromide
→
NCCC(=O)[O-].NCCC(=O)[O-].[Mg+2]
Magnesium β-alaninate

Edukte

—
resultant solution
—
2/3
—
Al
NS(=O)(=O)[O-].NS(=O)(=O)[O-].NS(=O)(=O)[O-].[Al+3]
aluminum sulfamate
NCCC(=O)O
β-alanine
O=C([O-])[O-].[Mg+2]
magnesium carbonate
OBr
hydroxybromide

Reagenzien

Keine

Lösungsmittel

O
water

Reaktionsbedingungen

Temperatur
75°CELSIUS
Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    SonstigeThe solution was evaporated at 60° C. under a vacuum of 252 m of Hg

Vorschrift

Magnesium β-alaninate was prepared by reacting 4.86 grams of β-alanine with 2.5 grams of basic magnesium carbonate (26.3% Mg) in 25 grams of water. The mixture was heated at 75° C. with agitation for one half hour. The hot solution was added to 100 grams of zirconyl hydroxybromide solution (17.5% Zr). To the resultant solution was added 14.2 grams of 2/3 basic aluminum sulfamate, Al(OH)2 (OSO2NH2) (9.19% Al, see U.S. Pat. No. 2,765,213 by S. M. Beekman) with agitation. The solution was evaporated at 60° C. under a vacuum of 252 m of Hg. The product contained 1.8% Al, 30.9% Zr, 0.53 Mg, 5.91% β-alanine and 5.3% sulfamates.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04017599uspto-grants-1977_04