Reaktion #414513

Reaktionsgleichung

3,3'-dibenzyloxy-4,4'-dimethoxystilbene

sodium hydrogen carbonate

sodium hypochlorite

→

rel-(S,S)-3,3'-Dibenzyloxy-4,4'-dimethoxy-stilbene oxide

Lösungsmittel

dichloromethane

Reaktionsbedingungen

Vorschrift

Mixture: 66.7 g 150 mmol) of 3,3'-dibenzyloxy-4,4'-dimethoxystilbene, 1500 ml of dichloromethane, 1500 ml of sodium hydrogen carbonate solution, 667 mg (1.5 mmol) of nickel-salene, 1.334 g (4.3 mmol) of benzyltributylammonium chloride, 250 ml of sodium hypochlorite solution (13% active chlorine).

Quelle