Reaktion #4077

Reaktionsgleichung

N-isopropyl-4-nitrosoaniline

sodium hydroxide

n-hexanol

→

N-isopropyl-p-phenylenediamine

Reaktionsbedingungen

Aufarbeitung

1. 1
   workup.DISTILLATIONBy vacuum distillation (95°-101° C. at 13.3-26.6 Pa), 31.3 g of product
2. 2
   Sonstigewere recovered
3. 3
   Sonstige(48.6 wt. % yield)

Vorschrift

Following essentially the procedure of Example 1, 66.0 g (0.25 mole) N-isopropyl-4-nitrosoaniline, 20 g (50%) sodium hydroxide and 264 g n-hexanol were kept at 100° C. for 1.5 hours. HPLC analysis of the reaction mixture indicated absence of the nitroso starting compound. By vacuum distillation (95°-101° C. at 13.3-26.6 Pa), 31.3 g of product were recovered (48.6 wt. % yield).

Quelle