Reaktion #363674

ord-8e3bbff1cfb14735b2fe03e17f2fd2f1

Reaktionsgleichung

CC(C)[C@H](N)CO
(1S)-1-Isopropyl-2-hydroxyethylamine
O=S(Cl)Cl
SOCl2
Cc1cc([N+](=O)[O-])ccc1N=C=S
2-methyl-4-nitrophenyl isothiocyanate
Cc1cc([N+](=O)[O-])ccc1N=C1N[C@@H](C(C)C)CS1
(4S)-2-(2-methyl-4-nitrophenylimino)-4-isopropyl-1,3-thiazolidine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

(1S)-1-Isopropyl-2-hydroxyethylamine was reacted with SOCl2 followed by 2-methyl-4-nitrophenyl isothiocyanate according to Method C2a to give (4S)-2-(2-methyl-4-nitrophenylimino)-4-isopropyl-1,3-thiazolidine. The thiazolidine was reacted with cyclopentyl bromide according to Method D2a to afford (4S)-2-(2-methyl-4-nitrophenylimino)-4-isopropyl-3-cyclopentyl-1,3-thiazolidine.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US06353006B1uspto-grants-2002_03