Reaktion #363672

ord-e57f662bf6bf414e97d9c41c6fe6e8a0

Reaktionsgleichung

CC(C)[C@@H](N)CO
(1R)-1-Isopropyl-2-hydroxyethylamine
O=S(Cl)Cl
SOCl2
Cc1cc([N+](=O)[O-])ccc1N=C=S
2-Methyl-4-nitrophenyl isothiocyanate
Cc1cc([N+](=O)[O-])ccc1N=C1N[C@H](C(C)C)CS1
(4R)-2-(2-methyl-4-nitrophenylimino)-4-isopropyl-1,3-thiazolidine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

(1R)-1-Isopropyl-2-hydroxyethylamine was reacted with SOCl2 followed by 2-Methyl-4-nitrophenyl isothiocyanate according to Method C2a to give (4R)-2-(2-methyl-4-nitrophenylimino)-4-isopropyl-1,3-thiazolidine. The thiazolidine was reacted with isobutyl bromide according to Method D2a to afford (4R)-2-(2-methyl -4-nitrophenylimino)-4-isopropyl-3-isobutyl-1,3-thiazolidine.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US06353006B1uspto-grants-2002_03