Reaktion #363619

ord-f63cc2a6d4e64a67b313d13df2fa9c98

Reaktionsgleichung

CC(C)C[C@H](N)CO
(1S)-1-(Hydroxymethyl)-3-methylbutylamine
Cc1ccc([N+](=O)[O-])cc1N=C=S
2-Methyl-5-nitrophenyl isothiocyanate
Cc1ccc([N+](=O)[O-])cc1N=C1N[C@@H](CC(C)C)CS1
(4S)-2-(2-methyl-5-nitrophenylimino)-4-isobutyl-1,3-thiazolidine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

(1S)-1-(Hydroxymethyl)-3-methylbutylamine was converted to (1S)-1-(chloromethyl)-3-methylbutanammonium chloride as described in Method B7a. 2-Methyl-5-nitrophenyl isothiocyanate was reacted with (1S)-1-(chloromethyl)-3-methylbutanammonium chloride according to Method C1a to give (4S)-2-(2-methyl-5-nitrophenylimino)-4-isobutyl-1,3-thiazolidine. The thiazolidine was reacted with isobutyl bromide according to Method D2a to afford (4S)-2-(2-methyl-5-nitrophenylimino)-3,4-diisobutyl-1,3-thiazolidine HCl salt.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US06353006B1uspto-grants-2002_03