Reaktion #359441

Reaktionsgleichung

2-(2,4-Di-t-pentylphenoxy)ethanoic acid

thionyl chloride

→

2-(2,4-di-t-pentyl-phenoxy)ethanoyl chloride

Reaktionsbedingungen

Aufarbeitung

1. 1
   Temperaturunder reflux on a steam-bath for 1.5 h
2. 2
   Temperaturto cool
3. 3
   workup.DISTILLATIONbefore being distilled under reduced pressure
4. 4
   Sonstigeto remove volatiles
5. 5
   workup.DISSOLUTIONThe residue was dissolved in 60-80 petroleum-ether (200 ml)
6. 6
   workup.DISTILLATIONthe solution was distilled under reduced pressure
7. 7
   Sonstigeto remove any remaining traces of volatiles

Vorschrift

2-(2,4-Di-t-pentylphenoxy)ethanoic acid (12.0 g, 0.041 mol) (CAS Registry Number 13402-96-5) and thionyl chloride (60 ml) were heated under reflux on a steam-bath for 1.5 h. The resulting yellow solution was allowed to cool before being distilled under reduced pressure to remove volatiles. The residue was dissolved in 60-80 petroleum-ether (200 ml) and the solution was distilled under reduced pressure to remove any remaining traces of volatiles, leaving 2-(2,4-di-t-pentyl-phenoxy)ethanoyl chloride as a red oil which was used without further purification.

Quelle