Reaktion #353802

Reaktionsgleichung

3-Dipropylamino-5-aminochroman

sodium azide

→

title compound

3-Dipropylamino-5-azidochroman

Lösungsmittel

water

Reaktionsbedingungen

Aufarbeitung

1. 1
   workup.STIRRINGAfter stirring at 5° C. overninght the solution
2. 2
   Sonstigepurified

Vorschrift

3-Dipropylamino-5-aminochroman (Example 14; 0.050 g, 0.20 mmol) was diazotized according to the procedure of Example 15. After stirring for 15 minutes, sodium azide (0.026 g, 0.4 mmol) in water (1.0 ml) was added. After stirring at 5° C. overninght the solution was worked-up and purified according to the procedure of Example 15 to give the title compound. Mp 167°-168° C. (oxalate).

Quelle