Reaktion #347734

Reaktionsgleichung

bisdichlorosilylmethane

1-hexene

→

bis(hexyldichlorosilyl)methane

Ausbeute 72.6%

Lösungsmittel

isopropanol

Reaktionsbedingungen

Aufarbeitung

1. 1
   Sonstigereacted for 2 hours
2. 2
   Temperaturat reflux under the dry nitrogen atmosphere
3. 3
   workup.DISTILLATIONVacuum distillation of the reaction products

Vorschrift

In the same apparatus and procedures as EXAMPLE 1, 8 g(0.04 mole) of bisdichlorosilylmethane, 12.7 g (0.15 mole) of 1-hexene and 120 μl of 1% chloroplatinic acid solution in isopropanol were placed and reacted for 2 hours at reflux under the dry nitrogen atmosphere. Vacuum distillation of the reaction products gave 11.1 g (118°-120° C./0.05 mmHg) of bis(hexyldichlorosilyl)methane in 72.6% yield.

Quelle