Reaktion #343279

Reaktionsgleichung

4,8-dimethylbicyclo[3.3.1]nona-7-en-2-yl methyl ether

hydrogen

→

title compound

Ausbeute 107.2%

nona-2-yl methyl ether

Ausbeute 107.2%

Lösungsmittel

ethanol

Reaktionsbedingungen

Aufarbeitung

1. 1
   Temperaturthe resulting mixture was heated
2. 2
   TemperaturAfter cooling
3. 3
   Filtrationthe Pd/C was filtered off
4. 4
   workup.DISTILLATIONthe ethanol was distilled off under reduced pressure

Vorschrift

To a solution of 1 g (5.6 mmol) of 4,8-dimethylbicyclo[3.3.1]nona-7-en-2-yl methyl ether [IB] in 10 ml of ethanol was added 0.1 g of 5% of Pd/C and the resulting mixture was heated with stirring at a hydrogen pressure of 20 atm and a reaction temperature of 70° C. for 6 hours. After cooling, the Pd/C was filtered off and the ethanol was distilled off under reduced pressure. The residue was subjected to column chromatography and eluate with toluene gave 0.95 g of the title compound, which had a camphor-like smell.

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