Reaktion #338895

Reaktionsgleichung

9,9-bis(4-(3-benzyloxy-4-nitrophenoxy)-phenyl)-2,7-di(1-adamantyl)-fluorene

4,6-di(1-adamantyl)-1,3-bis(3-benzyloxy-4-nitrophenoxy)benzene

→

9,9-bis(4-(4-amino-3-hydroxyphenoxy)-phenyl)-2,7-di(1-adamantyl)-fluorene

Ausbeute 88.7%

Reaktionsbedingungen

Aufarbeitung

1. 1
   Sonstigeobtained above (46.8 mmol)

Vorschrift

Next, a synthesis was performed in the same condition as in Synthesis example 1 except that 50.2 g of the 9,9-bis(4-(3-benzyloxy-4-nitrophenoxy)-phenyl)-2,7-di(1-adamantyl)-fluorene obtained above (46.8 mmol) was used in place of 39.0 g of 4,6-di(1-adamantyl)-1,3-bis(3-benzyloxy-4-nitrophenoxy)benzene mmol), thus obtaining 34.6 g of 9,9-bis(4-(4-amino-3-hydroxyphenoxy)-phenyl)-2,7-di(1-adamantyl)-fluorene (41.5 mmol; yield: 88.7%).

Quelle