Reaktion #335113

ord-afbb341023b643e2879f9ac38f5f0a86

Reaktionsgleichung

CCCCCCCCCCCCCCOc1ccccc1C(=O)OC
product
CCCCCCCCCCCCCCOc1ccccc1C(=O)OC
2-(Tetradecyloxy)benzoic acid methyl ester
[Al+3].[H-].[H-].[H-].[H-].[Li+]
lithium aluminum hydride
→
CCCCCCCCCCCCCCOc1ccccc1CO
title compound
CCCCCCCCCCCCCCOc1ccccc1CO
2-(Tetradecyloxy)benzenemethanol

Edukte

CCCCCCCCCCCCCCOc1ccccc1C(=O)OC
product
CCCCCCCCCCCCCCOc1ccccc1C(=O)OC
2-(Tetradecyloxy)benzoic acid methyl ester
[Al+3].[H-].[H-].[H-].[H-].[Li+]
lithium aluminum hydride

Reagenzien

Keine

Lösungsmittel

C1CCOC1
tetrahydrofuran

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    SonstigeThe product, 18.4 g, is obtained as colorless crystals

Vorschrift

The title compound is prepared by the procedure of Example 19 using 20.0 g of product from Example 17, 200 ml of dry tetrahydrofuran and 6.53 g of lithium aluminum hydride. The reaction is stirred at room temperature for 60 hours. The product, 18.4 g, is obtained as colorless crystals.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US05208247uspto-grants-1993_05