Reaktion #334889
ord-2c5f41d7c6974a6e82f3a5e8b4cec75f
Reaktionsgleichung
ethylene carbonate
→
ethylene carbonate
Ausbeute 96.6%
carbon dioxide
Ausbeute 27.6%
Edukte
Reagenzien
Lösungsmittel
Reaktionsbedingungen
Temperatur
135°CELSIUS
Detaillierte Bedingungen
See reaction.notes.procedure_details.
Vorschrift
A 50:1 mole ratio of ethylene carbonate:monoethylene glycol is heated with stirring under a nitrogen atmosphere for 88 hours at 135° C. using 0.2 percent Na2SnO3.3H2O as catalyst to give 96.6 percent ethylene carbonate conversion to a poly(alkylene carbonate) polyol with 27.6 percent carbon dioxide.