Reaktion #334888

ord-8a7eca64f5a648ddb4117baf4d3ae293

Reaktionsgleichung

O=C1OCCO1
ethylene carbonate
O=C1OCCO1
ethylene carbonate
Ausbeute 95.7%
O=C=O
carbon dioxide
Ausbeute 21.8%

Lösungsmittel

Reaktionsbedingungen

Temperatur
150°CELSIUS
Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

A 15:1 mole ratio of ethylene carbonate:diethylene glycol is heated with stirring under a nitrogen atmosphere for 8 hours at 150° C. using 1.0 percent Na2SnO3.3H2O as catalyst to give 95.7 percent ethylene carbonate conversion to a poly(alkylene carbonate) polyol with 21.8 percent carbon dioxide.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04709069uspto-grants-1987_11