Reaktion #334414

ord-101e106531384738ad69ad1cab1045f8

Reaktionsgleichung

FC(F)(F)C1(F)OC1(F)F
hexafluoropropylene oxide
FC(F)(F)C1(F)OC1(F)F
hexafluoropropylene oxide
O=C(C(F)(F)F)C(F)(F)F
hexafluoroacetone
C=C(C(F)(F)F)C(F)(F)F
hexafluoroisobutylene

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    Temperaturmaintained at a temperature in the range of about 400° to about 650° C.
  2. 2
    workup.ADDITIONcontaining a fluorinated catalyst (

Vorschrift

In the form of the present invention starting from hexafluoropropylene oxide, a vapor stream of hexafluoropropylene oxide is fed at any convenient flow rate, e.g., in the range of about 0.04 to about 0.06 g-mole/hr to a reactor maintained at a temperature in the range of about 400° to about 650° C. and containing a fluorinated catalyst (hereinafter described) for a residence time sufficient to for a vapor stream comprising hexafluoroacetone which is not isolated but forwarded directly to a heating zone of the reactor for conversion to hexafluoroisobutylene.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04705904uspto-grants-1987_11