Reaktion #310736

ord-111dd210d57e425787cb6ff3d4b6e9fa

Reaktionsgleichung

C[SiH](Cl)Cl
methyl dichlorosilane
C=CCCCCCCCC
1-decene
→
CCCCCCCCCC[Si](C)(Cl)Cl
methyl decyl dichlorosilane
Ausbeute 94.0%

Edukte

C[SiH](Cl)Cl
methyl dichlorosilane
C=CCCCCCCCC
1-decene

Reagenzien

[Cl][Pt-2]([Cl])([Cl])([Cl])([Cl])[Cl].[H+].[H+]
chloroplatinic acid

Lösungsmittel

CC(C)O
2-propanol

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    workup.ADDITIONwere charged to a reaction vessel
  2. 2
    Temperaturheated to about 100°-120° C. for six hours
  3. 3
    workup.DISTILLATIONdistilled at 110°-114° C. at 1-3 Torr

Vorschrift

2.25 Parts of methyl dichlorosilane, 4.04 parts of 1-decene and a solution containing about 0.0005 part of chloroplatinic acid catalyst in 0.006 part of 2-propanol were charged to a reaction vessel and heated to about 100°-120° C. for six hours. The product was vacuum distilled at 110°-114° C. at 1-3 Torr. 4.7 Parts (94% yield) of methyl decyl dichlorosilane was obtained.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04355062uspto-grants-1982_10