Reaktion #306690

ord-8b33147d851c48608e7e7a3f0279346a

Reaktionsgleichung

CC(C)(C)c1ccc(S(=O)c2ccc(C(C)(C)C)cc2)cc1
bis(4-tert-butylphenyl)sulfoxide
CC(C)(C)c1ccc(Br)cc1
4-tert-butylbromobenzene
→
CC(C)(C)c1ccc([S+](c2ccc(C(C)(C)C)cc2)c2ccc(C(C)(C)C)cc2)cc1.[Br-]
tris(4-tert-butylphenyl)sulfonium bromide

Edukte

CC(C)(C)c1ccc(S(=O)c2ccc(C(C)(C)C)cc2)cc1
bis(4-tert-butylphenyl)sulfoxide
CC(C)(C)c1ccc(Br)cc1
4-tert-butylbromobenzene

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    SonstigeThe intended compound was obtained by a similar manner to that
  2. 2
    Extraktionthe amount of water in the extraction
  3. 3
    Temperaturwas increased

Vorschrift

The intended compound was obtained by a similar manner to that in Synthesis Example 1 except that bis(4-tert-butylphenyl)sulfoxide instead of diphenyl sulfoxide and 4-tert-butylbromobenzene instead of chlorobenzene were used, and the amount of water in the extraction was increased.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US08202677B2uspto-grants-2012_06