Reaktion #3035

ord-1b9e3c51570840348769e6a40ddaa89d

Reaktionsgleichung

CC(C)(C)c1cc(C=O)cc(C(C)(C)C)c1O
3,5-di-tert-butyl-4-hydroxybenzaldehyde
CN1C(=O)CSC1=S
N-methylrhodanine
→
CN1C(=O)C(=Cc2cc(C(C)(C)C)c(O)c(C(C)(C)C)c2)SC1=S
title compound
Ausbeute 76.0%
CN1C(=O)C(=Cc2cc(C(C)(C)C)c(O)c(C(C)(C)C)c2)SC1=S
5-[[3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl]methylene]-3-methyl -2-thioxo -4-thiazolidinone
Ausbeute 76.0%

Edukte

CC(C)(C)c1cc(C=O)cc(C(C)(C)C)c1O
3,5-di-tert-butyl-4-hydroxybenzaldehyde
CN1C(=O)CSC1=S
N-methylrhodanine

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

The title compound was prepared in 76% yield from 3,5-di-tert-butyl-4-hydroxybenzaldehyde and N-methylrhodanine following the procedure of Example 1, m.p. >230° C.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US05731336uspto-grants-1998_03