Reaktion #2741

ord-a4163a4ffca54f15a71dce74978d3a8a

Reaktionsgleichung

CCCCC[Si]1(c2ccccc2)CCC(c2ccc(-c3cc(F)c(O)c(F)c3)cc2)CC1
4-(4-(4-n-pentyl-4-phenyl-4-silacyclohexyl)phenyl) -2,6-difluorophenol
CCCCCCCC[C@H](F)CO
(S)-2-fluoro-1-decanol
→
CCCCCCCC[C@@H](F)COc1c(F)cc(-c2ccc([C@H]3CC[Si@H](CCCCC)CC3)cc2)cc1F
(R)-4-(4-(trans-4-n-pentyl-4-silacyclohexyl)phenyl)-1-(2-fluorodecyloxy)-2,6-difluorobenzene

Edukte

CCCCC[Si]1(c2ccccc2)CCC(c2ccc(-c3cc(F)c(O)c(F)c3)cc2)CC1
4-(4-(4-n-pentyl-4-phenyl-4-silacyclohexyl)phenyl) -2,6-difluorophenol
CCCCCCCC[C@H](F)CO
(S)-2-fluoro-1-decanol

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    Sonstigeobtaining the intended compound

Vorschrift

The general procedure of Example 1 was repeated using 4-(4-(4-n-pentyl-4-phenyl-4-silacyclohexyl)phenyl) -2,6-difluorophenol and (S)-2-fluoro-1-decanol, thereby obtaining the intended compound.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US05730902uspto-grants-1998_03