Reaktion #2737

ord-79a844ae48a5409c8f92ead50c3e3c88

Reaktionsgleichung

CCCCCCC[C@H]1CC[C@H]([SiH]2CCC(c3cc(F)c(O)c(F)c3)CC2)CC1
4-(4-(trans-4-n-heptylcyclohexyl)-4-silacyclohexyl)-2,6-difluorophenol
CCCCCCC[C@H](C)O
(S)-2-nonanol
→
CCCCCCC[C@@H](C)Oc1c(F)cc([C@H]2CC[Si@H]([C@H]3CC[C@H](CCCCCCC)CC3)CC2)cc1F
(R)-4-(trans-4-(trans-4-n-heptylcyclohexyl)-4-silacyclohexyl)-1-(1-methyloctyloxy)-2,6-difluorobenzene

Edukte

CCCCCCC[C@H]1CC[C@H]([SiH]2CCC(c3cc(F)c(O)c(F)c3)CC2)CC1
4-(4-(trans-4-n-heptylcyclohexyl)-4-silacyclohexyl)-2,6-difluorophenol
CCCCCCC[C@H](C)O
(S)-2-nonanol

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    Sonstigeobtaining the intended compound

Vorschrift

The general procedure of Example 1 was repeated using 4-(4-(trans-4-n-heptylcyclohexyl)-4-silacyclohexyl)-2,6-difluorophenol and (S)-2-nonanol, thereby obtaining the intended compound.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US05730902uspto-grants-1998_03