Reaktion #2687

Reaktionsgleichung

HCl

n-nonadecyl-n-tetradecyl-n-decylcarbinol

calcium chloride

→

n-nonadecyl-n-tetradecyl-n-decylmethylchloride

Lösungsmittel

methylene chloride

Reaktionsbedingungen

Aufarbeitung

1. 1
   WaschenThe product mixture is then washed with 1 liter of a 10% sodium carbonate solution
2. 2
   TrocknenThe organic layer is dried with magnesium sulfate
3. 3
   Sonstigethe methylene chloride is evaporated off

Vorschrift

One mole of n-nonadecyl-n-tetradecyl-n-decylcarbinol is added to 0.2 liters of methylene chloride and 0.32 moles calcium chloride. Approximately 1.5 moles of HCl gas is slowly bubbled through the solution. The product mixture is then washed with 1 liter of a 10% sodium carbonate solution. The organic layer is dried with magnesium sulfate and the methylene chloride is evaporated off to give n-nonadecyl-n-tetradecyl-n-decylmethylchloride.

Quelle