Reaktion #2682

Reaktionsgleichung

tri-n-decylcarbinol

trimethylaluminum

→

tri-n-decylmethylmethane

Ausbeute 70.0%

Lösungsmittel

methylene chloride

Reaktionsbedingungen

Aufarbeitung

1. 1
   Temperaturto warm to room temperature
2. 2
   SonstigeThe reaction was quenched with water
3. 3
   Waschenwashed with 0.1 liter of a 20% HCl solution
4. 4
   TrocknenThe organic layer was dried with magnesium sulfate
5. 5
   Sonstigethe methylene chloride removed

Vorschrift

Alternatively, the 0.1 moles of the synthesized tri-n-decylcarbinol was added to 0.2 liters of methylene chloride. The mixture was covered with a blanket of nitrogen and cooled to 0° C. 0.050 mole titanium tetrachloride was added to the mixture and the solution was stirred 2-3 hours at 0° C. 0.066 mole trimethylaluminum was added and the mixture was allowed to warm to room temperature. The reaction was quenched with water and washed with 0.1 liter of a 20% HCl solution. The organic layer was dried with magnesium sulfate and the methylene chloride removed to give a yield of 70% tri-n-decylmethylmethane.

Quelle