Reaktion #2680

Reaktionsgleichung

HCl

tri-n-decylcarbinol

calcium chloride

→

tri-n-decylmethylchloride

Ausbeute 90.0%

Lösungsmittel

methylene chloride

Reaktionsbedingungen

Aufarbeitung

1. 1
   WaschenThe product mixture is then washed with 1 liter of a 10% sodium carbonate solution
2. 2
   TrocknenThe organic layer is dried with magnesium sulfate
3. 3
   Sonstigethe methylene chloride evaporated off

Vorschrift

One mole of tri-n-decylcarbinol was added to a mixture of 0.2 liters of methylene chloride and 0.32 moles calcium chloride. Approximately 1.5 moles of HCl gas was slowly bubbled through the solution. The product mixture is then washed with 1 liter of a 10% sodium carbonate solution. The organic layer is dried with magnesium sulfate and the methylene chloride evaporated off to give a 90% yield of tri-n-decylmethylchloride.

Quelle