Reaktion #2485162

ord-82296c8edf8c4dcbacd7dc20b5559dae

Reaktionsgleichung

CCC(=O)O.C[C@]12CC[C@H]3[C@@H](CCC4=CCCC[C@@]43C=O)[C@@H]1CC[C@@H]2O
17β-hydroxy-4-androsten-19-one propionate
CCC(=O)O.C[C@H]1CCC=C2CC[C@H]3[C@@H]4CC[C@H](O)[C@@]4(C)CC[C@@H]3[C@]21C=O
17β-hydroxy-1α-methyl-4-androsten-19-one propionate
→
C[C@]12CC[C@H]3[C@@H](CCC4=CCCC[C@@]43C=O)[C@@H]1CC[C@@H]2O
17β-hydroxy-4-androsten-19-one

Edukte

CCC(=O)O.C[C@]12CC[C@H]3[C@@H](CCC4=CCCC[C@@]43C=O)[C@@H]1CC[C@@H]2O
17β-hydroxy-4-androsten-19-one propionate
CCC(=O)O.C[C@H]1CCC=C2CC[C@H]3[C@@H]4CC[C@H](O)[C@@]4(C)CC[C@@H]3[C@]21C=O
17β-hydroxy-1α-methyl-4-androsten-19-one propionate

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

Substituting 17β-hydroxy-4-androsten-19-one propionate for the 17β-hydroxy-1α-methyl-4-androsten-19-one propionate above results in the preparation of 17β-hydroxy-4-androsten-19-one.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04022769uspto-grants-1977_05