Reaktion #2446056

Reaktionsgleichung

acetonitrile

1-bromo-2-[(2-bromoethyl)disulphanyl]ethane

N-methylpyrrolidone

2-picoline

→

1,1′-(Disulphanediyldiethane-2,1-diyl)bis(2-methylpyridinium)dibromide

Reaktionsbedingungen

Aufarbeitung

1. 1
   workup.STIRRINGwith stirring at 80° C. for 30 minutes
2. 2
   workup.STIRRINGstirring
3. 3
   Temperaturis maintained at 80° C. for 90 minutes
4. 4
   TemperaturAfter cooling
5. 5
   Sonstigethe solid obtained
6. 6
   Filtrationis filtered off
7. 7
   Waschenwashed with 100 ml of acetonitrile
8. 8
   Sonstigedried

Vorschrift

A mixture of 56 g of 1-bromo-2-[(2-bromoethyl)disulphanyl]ethane and 15 ml of N-methylpyrrolidone (NMP) is introduced dropwise into 35 g of 2-picoline with stirring at 80° C. The mixture (white suspension) is kept with stirring at 80° C. for 30 minutes, 100 ml of acetonitrile are added, and stirring is maintained at 80° C. for 90 minutes. After cooling, the solid obtained is filtered off, washed with 100 ml of acetonitrile and then dried.

Quelle