Reaktion #2383688

ord-7047ce36165548e0b0dda930a92fa923

Reaktionsgleichung

[Ca+2].[O-2]
calcium oxide
[Al+3].[Al+3].[O-2].[O-2].[O-2]
aluminum oxide
CCC1CCCCC1N
2-ethylcyclohexylamine
→
CCc1ccccc1N
o-Ethylaniline
Ausbeute 95.0%

Edukte

[Ca+2].[O-2]
calcium oxide
[Al+3].[Al+3].[O-2].[O-2].[O-2]
aluminum oxide
CCC1CCCCC1N
2-ethylcyclohexylamine

Reagenzien

[Pd]
palladium

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    Sonstigea reaction temperature of 250° C.

Vorschrift

The procedure described in Example 27 is followed, using a reaction temperature of 250° C. and a catalyst which contains 0.5% by weight of palladium on a mixture of 19.4% by weight of calcium oxide and 80.6% by weight of aluminum oxide, and starting from 2-ethylcyclohexylamine. o-Ethylaniline (boiling point=210° C.) is obtained in a yield of 95% of the theory.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04429155uspto-grants-1984_01