Reaktion #2359

Reaktionsgleichung

ε-caprolactone

p-dioxanone

→

ε-CAPROLACTONE p-DIOXANONE

Reaktionsbedingungen

Aufarbeitung

1. 1
   SonstigeThe copolymer was dried under vacuum (0.1 mm Hg) at 80° C. for about 80 hours
2. 2
   Sonstigeto remove any unreacted monomer
3. 3
   Sonstigeat 25° C
4. 4
   Sonstigeat room temperature

Vorschrift

The procedure in Example 5A is substantially repeated except that 45.7 grams (0.40 mole) of ε-caprolactone and 61.3 grams (0.60 mole) of p-dioxanone were used. The copolymer was dried under vacuum (0.1 mm Hg) at 80° C. for about 80 hours to remove any unreacted monomer. The copolymer had an inherent viscosity of 0.18 dL/g in HFIP at 25° C. The copolymer was a liquid at room temperature. The molar ratio of PCL/PDS was found to be 46.7/53.3 by proton NMR.

Quelle