Reaktion #2281040

Reaktionsgleichung

isopulegol

→

d-Isopulegol

Lösungsmittel

water

Reaktionsbedingungen

Aufarbeitung

1. 1
   workup.ADDITIONwas added to the reaction mixture

Vorschrift

The catalyst solution obtained in Example 7-1 was cooled to 0 to 5° C., and 1.54 g (10.0 mmol) of l-citronellal was added dropwise to the solution, followed by stirring at 0 to 5° C. overnight. After completion of the reaction, 2 ml of water was added to the reaction mixture, and an organic layer was analyzed with gas chromatography. As a result, substrate conversion was 89.2%, isopulegol conversion was 88.1%, and the ratio of l-n-isopulegol to the other isomers was 96.9:3.1.

Quelle